SEMESTER_02 (Calcutta University)
Course Syllabus
(Total 16 Lectures)
Chemical Thermodynamics
1st law of Thermodynamics: Intensive and extensive variables; state and path functions; isolated, closed and open systems; zeroth law of thermodynamics; Concept of heat, work, internal energy and statement of first law; enthalpy, H; relation between heat capacities, calculations of q, w, ΔU and ΔH for reversible, irreversible and free expansion of gases (ideal and van der Waals) under isothermal and adiabatic conditions; Joule’s experiment and its consequence.
Thermochemistry: Standard states; Heats of reaction; enthalpy of formation of molecules and ions and enthalpy of combustion and its applications; Laws of thermochemistry; bond energy, bond dissociation energy and resonance energy from thermochemical data, Kirchhoff’s equations; Adiabatic flame temperature.
Chemical Thermodynamics II
Second Law: Need for a Second law; statement of the second law of thermodynamics; Concept of heat reservoirs and heat engines; Carnot cycle; Carnot engine and refrigerator; Kelvin – Planck and Clausius statements and equivalence of the two statements with entropic formulation; Carnot’s theorem; Values of §dQ/T and Clausius inequality; Physical concept of Entropy; Entropy is a measure of the microscopic disorder of the system. Entropy change of systems and surroundings for various processes and transformations; Entropy and unavailable work; Auxiliary state functions (G and A) and their variation with T, P and V. Criteria for spontaneity and equilibrium.
Thermodynamic relations: Maxwell’s relations; Gibbs- Helmholtz equation, Joule-Thomson experiment and its consequences; inversion temperature; Joule-Thomson coefficient for a van der Waals gas; General heat capacity relations
Reference Books
- Levine, I. N. Physical Chemistry, 6th Edition , McGraw-Hill India
- Castellan, G. W. Physical Chemistry, Narosa
- McQuarrie, D. A. & Simons, J. D. Physical Chemistry: A Molecular Approach, Viva Press
- Kapoor K.L, A Text Book Of Physical Chemistry , McGraw Hill India
- Engel, T. & Reid, P. Physical Chemistry, 3rd Edition ,Pearson India
- Atkins, P. W. & Paula, J. de Atkins’ Physical Chemistry, 10th Edition, Oxford University Press
- Maron, S. & Prutton , Physical Chemistry
- Ball, D. W. Physical Chemistry, Thomson Press
- Mortimer, R. G. Physical Chemistry, 2nd Edition, Elsevier
- Glasstone, S. & Lewis, G.N. Elements of Physical Chemistry
- Rakshit, P.C., Physical Chemistry,Sarat Book House
- Moore, W. J. Physical Chemistry, Orient Longman
- Denbigh, K. The Principles of Chemical Equilibrium ,Cambridge
- Zemansky, M. W. & Dittman, R.H. Heat and Thermodynamics, Tata-McGraw- Hil
- Glasstone, S. An Introduction to Electrochemistry, East-West Press.
- Klotz, I.M., Rosenberg, R. M.Chemical Thermodynamics:Basic Concepts and Methods , 7th Edition, Wiley
Course Features
- Students 344 students
- Max Students500
- Duration16 week
- Skill leveladvanced
- LanguageEnglish
- Re-take courseN/A
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Introduction to Thermodynamics
AR Sir's Lectures on Physical Chemistry (Aspiration Academy)
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First Law of Thermodynamics
AR Sir's Lectures on Physical Chemistry (Aspiration Academy)
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Thermochemistry
AR Sir's Lectures on Physical Chemistry (Aspiration Academy)
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Second Law of Thermodynamics
AR Sir's Lectures on Physical Chemistry (Aspiration Academy)
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